ABSTRACT Excessive phosphorus (P) applications can increase nutrient levels in the soil, facilitating its transference to aquatic environments and causing contamination. Thus, the environmental P threshold (P-threshold) is a tool to establish a sound level of P in the soil, in which P values below the threshold are harmless to the environment. This study aimed to establish a P-threshold equation for the soils of Mato Grosso State, Brazil. Twenty samples of representative soils from the main swine production regions of the State were collected. These samples were characterized chemically and in terms of P adsorption capacity, then incubated with P rates for 30 days. After incubation, the water-soluble P content (P-water) and the available P content were determined by Mehlich-1 method (P-Mehlich-1). The relationship between P-water and P-Mehlich-1 allowed the determination of the P-Mehlich-1 content from which the amount of nutrient in water increases abruptly, establishing this point as the limit P (P-limit). Subsequently, the P-limit values were plotted against the clay content of the soils, and the resulting equation was used to calculate the P-threshold by adding a safety margin of 20 % to the P-limit versus clay equation. The model was tested on 120 soil samples from Mato Grosso State, and it was able to separate them into two groups with low and high P-water, classified as below or above P-threshold, respectively. Based on that, the simplified equation “P-threshold (mg dm-3) = 13 + 0.5 * % clay” was proposed.

ABSTRACT Soils with low potassium (K) availability require corrective fertilization for grain crops. The recommended rate to increase K availability up to the critical level depends on the soil K buffering capacity (KBC). This study aimed to quantify the KBC and recalculate the rates necessary to reach the K critical level in 23 soils from Southern Brazil. Soil samples were incubated with six K rates, that were thus grouped according to CECpH7.0: below 7.5 cmolc dm-3 (0, 30, 60, 90, 120 and 180 kg K2O ha-1); from 7.6 to 15 cmolc dm-3 (0, 30, 60, 120, 180 and 240 kg K2O ha-1) and from 15.1 to 30 cmolc dm-3 (0, 30, 60, 120, 240 and 360 kg K2O ha-1). The soil test K (STK) was extracted by Mehlich-1 and the fertilizer rates necessary to increase the STK by 1 mg dm-3 were quantified. The KBC values were correlated with a suite of soil testing metrics. The relationship between the cation exchange capacity (CECpH7.0) and KBC was modeled, and a linear-plateau equation presented the best fit. The K rates were calculated using the following equation: K rate = ( Critical Level − S T K ) × K B C and were compared with the current rate indicated by the Local Soil Fertility Committee. The K fertilizer rates by KBC were about 2.5 times higher than the values currently indicated, and the largest differences were observed in soils with low STK and high CECpH7.0.

ABSTRACT The phosphorus (P) rates recommended for corrective fertilization-P of soils from southern Brazil may be insufficient to reach the critical level for optimal plant growth. This study aimed to quantify the fertilizer-P rates for total correction fertilization with varying soil buffering capacity in the states of Rio Grande do Sul (RS) and Santa Catarina (SC). Soil samples from 0.00-0.10 and 0.10-0.20 m layers were collected from 41 locations distributed in both states. Twelve P rates were applied to each soil, varying between 0 and 100 % of the maximum adsorption capacity (P-max), and incubated for 20 days. After incubation, the extractable P was determined by Mehlich-1. Based on the relationship between applied rates and extracted P, the P buffer capacity (trP_M1) of the soils was quantified, relating it to soil properties. The trP_M1 values, that is, amounts of P2O5 required to increase 1 mg dm-3 of P extracted by Mehlich-1, varied between 2.4 and 34.5 kg ha-1 of P2O5. A multiple explanatory equation for the variable P was generated, in which only P-max, clay content, and initial P availability have a significant effect. The P buffer capacity was significantly higher in the soils with the highest clay content, and there was a reduction in trP_M1 for soils with higher initial P availability. Considering 270 soil samples with low P, the P rate to reach the sufficient levels may be 2-folds higher than the values currently indicated for the RS and SC states, especially for soils with more than 40 % of clay. Phosphorus rates for corrective fertilization must be based on the soil clay content and in P initial availability. The fertilizer-P in clayey soils must be increased.